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| Untersuchte Arbeit: Seite: 49, Zeilen: 1-6 |
Quelle: Yin 2004 Seite(n): 11, Zeilen: 7-11 |
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| The first system was introduced by George et al. [Geo93, Geo93a, Ver93]. A free radical initiator, such as 2,2'-azobisisobutyrolnitrile (AIBN) or benzoyl peroxide (BPO) is used in conjunction with TEMPO. The second system is a "unimolecular system", in which alkoxyamine dissociates to produce both the initiating radical and the mediating nitroxide radical [Haw96, Haw96a, Tsa02].
[Geo93] Georges, M. K.; Veregin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Macromolecules 1993, 26, 2987. [Geo93a] Georges, M. K.; Veregin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Polym. Mater. Sci. Eng. 1993, 68, 6. [Haw96] Hawker, C.J.; Barclay, G.G.; Orellana, A.; Dao, J.; Devonport, W. Macromolecules, 1996, 29, 5245. [Haw96a] Hawker, C.J.; Barclay, G.G.; Dao, J. J. Am. Chem. Soc. 1996, 118, 11467. [Tsa02] Tsarevsky, N.V.; Sarbu, T.; Gobelt, B.; Matyjaszewski, K. Macromolecules 2002, 35, 6142. [Ver93] Veregin, R. P. N.; Georges, M. K.; Kazmaier, P. M.; Hamer, G. K. Macromolecules, 1993, 26, 5316. |
The first class, as introduced by George et al., is a “bimolecular system”, in which a conventional free radical initiator, such as 2,2’-azobisisobutyrolnitrile (AIBN) or benzoyl peroxide (BPO) is used in conjunction with TEMPO.10, 47, 59 The second class is a “unimolecular system”, in which alkoxyamine dissociate to produce both the initiating radical and the mediating nitroxide radical.13, 54, 60
10. Georges, M.K.; Veregin, R.P.N.; Kazmaier, P.M.; Hamer, G.K. Macromolecules, 1993, 26, 2987. 13. Tsarevsky, N.V.; Sarbu, T.; Gobelt, B.; Matyjaszewski, K. Macromolecules, 2002, 35, 6142 47. Georges, M.K.; Veregin, R.P.N.; Kazmaier, P.M.; Hamer, G.K. Polym. Mater. Sci. Eng., 1993, 68, 6. 54. Hawker, C.J.; Barclay, G.G.; Orellana, A.; Dao, J.; Devenport, W. Macromolecules, 1996, 29, 5245. 59. Veregin, R.P.N.; Georges, M.K.; Kazmaier, P.M.; Hamer, G.K. Macromolecules, 1993, 26, 5316. 60. Hawker, C.J.; Barclay, G.G.; Dao, J. J. Am. Chem. Soc., 1996, 118, 11467. |
No source given. Nothing has been marked as a citation. |
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