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| Untersuchte Arbeit: Seite: 46, Zeilen: 3-5, 7-11 |
Quelle: Yamada and Zetterlund 2002 Seite(n): 149, 162, Zeilen: 149:32-34; 162:25-29 |
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| Chain transfer can occur to all the substances present in a polymerization system and T can be employed to effectively reduce the molecular weight or to introduce designated end groups.
Chain transfer will continue until some termination process occurs. Termination is perhaps the most complex of the elementary reactions in free radical polymerisation as it constitutes the consecutive events of polymer radicals undergoing translational diffusion to come into relative proximity of one another, segmental diffusion whereby the chain ends approach one another, and finally chemical reaction. |
[page 149]
Chain transfer can occur to all the substances present in a polymerization system, and T can be employed to effectively reduce the molecular weight or to introduce designated end groups. [page 162] Termination is perhaps the most complex of the elementary reactions in free-radical polymerization as it constitutes the consecutive events of polymer radicals undergoing translational diffusion to come into relative proximity of one another, segmental diffusion whereby the chain ends approach one another, and finally chemical reaction.146 146. S. Beuermann and M. Buback, in Controlled Radical Polymerization, K. Matyjaszewski, ed., ACS Symposium Series 685, 1998, p. 84. |
No source given; although identical nothing has been marked as a citation. |
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